Product ID:EMPIRE 20, 13042
MSDS Date:08/14/1989
FSC:6810
NIIN:00N015784
MSDS Number: BKRNH

DOW CHEMICAL COMPANY

2020 DOW CENTER
MIDLAND, MI 48640
US

Emergency Phone: 517-636-4400

Info Phone: 800-447-4369

Cage: 0BHP4

THE DOW CHEMICAL COMPANY

368 MIDLAND, MI 48674-1776 US

Telephone: 800-258-2436 / 989-636-0773

Cage: 0BHP4

WATER AND OTHER PROPRIETARY INGREDIENTS

Fraction By Weight: 70%

CHOLINESTERASE DETERM.SUPPORTIVE

RTECS: 9999999ZZ

IS PERMITTED, BURY IN ISOLATED, NON-CROP

RTECS: 9999999ZZ

SUPPLIES. KEEP OUT OF DOMESTIC/NATURAL WATER

RTECS: 9999999ZZ

CHLORPYRIFOS (SARA III)

CAS: 2921-88-2

RTECS: TF6300000

Fraction By Weight: 20%

OSHA PEL S, 0.2 MG/M3

ACGIH TLV: S, 0.2 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

PROPRIETARY PETROLEUM SOLVENT

Fraction By Weight: 10%

LD50 LC50 Mixture:LD50 (ORAL,RAT) >25,000 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: ESSNTL NONIRRIT TO EYES. SKIN:
PRLNGD CONTACT IS ESSNTL NONIRRIT TO SKIN. ABSORB: SINGLE PRLNGD
EXPOS IS NOT LIKELY TO RSLT IN MATL BEING ABSORB THROUGH SKIN IN
HARMFUL AMTS. INGEST: SINGLE DOSE ORAL TOXICITY IS EXTREMELY LOW.
NO HAZ ANTICIPATED FROM INGEST INCIDENTAL TO INDUST EXP. INHAL:
(SEE EFTS OF OVEREXPOS).
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: VAP UNLIKELY DUE TO PHYS PROPERTIES.
SYSTEMIC EFTS: CHLORPYRIFOS IS CHOLINESTERASE INHIBITOR.
CHLORPYRIFOS PRDCE MILD ADRENAL EFTS WHEN FED TO RATS, BUT ONLY AT
DOSES THAT GREATLY EXCEEDED A NY EXPOS THAT WOULD BE RECEIVED
DURING USE OF PROD. EXCESSIVE EXPOS TO SOLV MAY CAUSE RESP IRRIT &
CNS (SEE SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IRRIGATE IMMED W/WATER FOR AT LEAST 15 MINUTES. SKIN:
WASH OFF IN FLOWING WATER/SHOWER. INGEST: INDUCE VOMIT IF LARGE
AMOUNTS INGEST. CONSULT MD. INHAL: REMOVE TO FRESH AIR IF EFTS
OCCUR. CONSUL T MD. NOTE TO PHYS: ATROPINE BY IV ADMIN IS
PREFERABLE ANTIDOTE. OXIMES MAY/MAY NOT BE THERAPEUTIC BUT RECOMND
THEY NOT BE USED IN PLACE OF ATROPINE. SUGGEST SERUM AND/OR RBC
(SEE INGRED 4).

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER FOG, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE
SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DOES NOT BURN.

Spill Release Procedures:SWEEP UP INTO PLASTIC BAGS USING SWEEPING
COMPOUND.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
CERTAIN OPERATIONS, USE A NIOSH/MSHA APPROVED AIR-PURIFYING
RESPIRATOR.
Ventilation:CONTROL AIRBORNE CONC BELOW EXPOS GUIDELINE. GOOD GENERAL
VENT SHOULD BE SUFFICIENT FOR MOST CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXPOS: EFTS; EXCESSIVE EXPOS TO CHLORPYRIFOS/SOLV UNLIKELY
DUE TO PHYS STATE. TERATOLOGY: CHLORPYRIFOS DIDN'T CAUSE BIRTH
DEFECTS IN ANIMALS; OTHER EFTS WERE SEEN IN FETUS ONLY AT DOSES WH
ICH CAUSED TOXIC EFTS TO MOTHER. REPRODEFTS: IN ANIMAL STUDIES,
CHLORPYRIFOS HAS BEEN SHOWN NOT TO INTERFERE W/REPROD.

Boiling Pt:B.P. Text:212F,100C
Vapor Pres:17.5MMHG
Vapor Density:<1
Spec Gravity:1.03
Solubility in Water:DISPERSES IN WATER
Appearance and Odor:WHITE SUSPENSION, SLIGHT SOLVENT ODOR

Stability Indicator/Materials to Avoid:YES
BASE. CONSULT MANUFACTURER FOR SPECIFIC CASES.
Stability Condition to Avoid:AVOID HEATING ABOVE 50 C FOR EXTENDED
PERIODS-LOSS OF ACTIVE INGREDIENT MAY RESULT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, ETHYL SULFIDE,
DIETHYL SULFIDES, NITROGEN OXIDES.

Waste Disposal Methods:DON'T CONTAM FOOD, FEED, WATER BY
STORAGE/CLEANING OF EQUIP. OPEN BURNING PROHIB. PESTICIDE, SPRAY
MIXTURE/RINSE WATER THAT CAN'T BE USED ACCRD TO LABEL INSTRUCTIONS
MUST BE DISPOSED ACCRD TO APPLIC F ED, STATE/LOCAL PROC. IF BURIAL
(SEE INGRED 5).

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.